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Arrays of quasi-hexagonally ordered silica nanopillars with independently controlled areal density, diameter and height gradients

Tuesday, February 24, 2015 4:26
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Where size matters

A consecutive fabrication approach of independently tailored gradients of the topographical parameters distance, diameter and height in arrays of well-ordered nanopillars on smooth SiO 2 –Si-wafers is presented. For this purpose, previously reported preparation techniques are further developed and combined. First, self-assembly of Au-salt loaded micelles by dip-coating with computer-controlled pulling-out velocities and subsequent hydrogen plasma treatment produce quasi-hexagonally ordered, 2-dimensional arrays of Au nanoparticles (NPs) with unidirectional variations of the interparticle distances along the pulling direction between 50–120 nm. Second, the distance (or areal density) gradient profile received in this way is superimposed with a diameter-controlled gradient profile of the NPs applying a selective photochemical growth technique. For demonstration, a 1D shutter is used for locally defined UV exposure times to prepare Au NP size gradients varying between 12 an…

Burcin Özdemir, Wenting Huang, Alfred Plettl and Paul Ziemann

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Source: http://nanochemistry.blogspot.com/2015/02/arrays-of-quasi-hexagonally-ordered.html

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