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P-N junctions in graphene developed using self-assembled monolayers

Tuesday, December 11, 2012 10:30
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Researchers from Georgia Tech have developed a new low-temperature method to dope graphene films using self-assembled monolayers (SAM) that modify the interface of graphene and its support substrate. Using this method the researchers developed graphene p-n junctions.

Graphene wafer with p-n junctions

The researchers used CVD to grow graphene on copper film and then transferred it to silicon dioxide substrates that were functionalized with the self-assembled monolayers. Thus they have shown that you can make fairly well doped p-type and n-type graphene controllably by patterning the underlying monolayer instead of modifying the graphene directly. All previous methods (such as substitution of carbon atoms for nitrogen atoms, compounds addition or graphene ribbons edge modification) or had disrupted the graphene lattice which reduced the electron mobility and the devices were not stable.

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