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Preparation and characterization of 1-naphthylacetic acid–silica conjugated nanospheres for enhancement of controlled-release performance

Friday, December 21, 2012 10:52
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Where size matters

Mingming Ao, Yuncong Zhu, Shun He, Deguang Li, Pingliang Li, Jianqiang Li and Yongsong Cao

Chemical pesticides have been widely used to increase the yield and quality of agricultural products as they are efficient, effective, and easy to apply. However, the rapid degradation and low utilization ratio of conventional pesticides has led to environmental pollution and resource waste. Nano-sized controlled-release formulations (CRFs) can provide better penetration through the plant cuticle and deliver the active ingredients efficiently to the targeted tissue. In this paper we reported novel conjugated nanospheres derived from 1-naphthylacetic acid (NNA), 3-aminopropyltriethoxysilane (APTES) and tetraethyl orthosilicate and their application as a controlled-release plant growth regulator. The NNA and APTES conjugate was prepared through a covalent cross-linking reaction and subsequent hydrolyzation and polycondensation to synthesize NNA–silica nanospheres. The release data indicated that the release of NNA was by non-Fickian transport and increased as particle size decrease…

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