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During years I have many times tried to understand what happens in electrolysis and every time I have been forced to to admit that I do not! Very embarrassing observation. I have tried to gain wisdom from an old chemistry book with 1000 pages again and again but always in vain. This is especially embarrassing because a unified theory builder to be taken seriously is expected to build brave new brane worlds in 11 or 12 dimensions to possibly explain a possible detected particle at mass 750 GeV at LHC instead of trying to understand age old little problems solved aeons ago. The wau-coefficient of chemistry is zero as compared to the awesome 10500 of M-theory.
Energetics has been my personal problem (besides funding). I learn from chemistry book that an electric field – say voltage of 2 V per 1 mm splits molecules to ions. The bond energies of molecules are in few eV range. For instance, O-H bond has 5 eV energy. V= 2V/mm electric field corresponds to electrostatic energy E=eVd∼ 2-10 eV energy gain for a unit charge moving from the end of the bond to the other one. This is incredibly small energy and to my understanding should have absolutely no effect to the state molecule. Except that it has!
A heretic thought: could it be that chemists have just accepted this fact (very reasonable!) and built their models as mathematical parameterizations without any attempt to understand what really happens? Could the infinite vanity of theoretical physicists have prevented them from lowering themselves to the intellectual level of chemists and prevented them from seeing that electrolysis is not at all understood?
In order that this kind of energy would have so drastic effect as splitting molecule to pieces, the system molecule + yet unidentified “something” must be in critical state. Something at the top of hill so that even slightest perturbation makes it fall down. The technical term is criticality or even quantum criticality.
What produces quantum criticality against charge separation? What is this unidentified “something” besides the system? Magnetic body carrying dark matter! This is the answer in TGD Universe. The TGD inspired model assumes that the protons transform to dark protons at dark magnetic flux tubes possibly carrying monopole flux. If these protons form dark nuclei the liberated dark nuclear energy can split further O-H bonds and transform protons to dark phase. The energy needed is about 5 eV and is in the nuclear binding energy scale scaling as 1/heff (like distance) if the size scale of dark protons proportional to heff/h is 1 nm. One would have heff/h≈ 106: the size scale of DNA codons – not an accident in TGD Universe. The liberated dark nuclear energy can ionize other molecules such as KOH, NaOH, HCl, Ca(OH)2, CaO,…
Entire spectrum of values of heff/h is possible. For laser pulse induced fusion (see the article ) assumed to induce longitudinal compression one would have heff/h≈ 103. Dark nuclear physics with non-standard values of Planck constant would be a crucial element of electrolysis. Condensed matter physics and nuclear physics would not live in totally separate compartments and dark matter an ordinary matter would interact! How humiliating for theoreticians! I do not hear the derisive laughter of superstring theoreticians anymore!
Ordinary electrolysis would thus produce dark nuclei. The problem is that most of them would leak out from the system along dark flux tubes and potentially available nuclear energy is lost! As also various elements so badly needed by modern techno-society! For instance, in the splitting of water to hydrogen, the flux tubes assignable to the beam containing hydrogen would take the dark nuclei away. Could one transform dark nuclei to ordinary ones?
But why metals? The surface of metal in external electric field carries negative charge density of conduction electrons. Could it be that they attract the positively charged dark nuclei from the magnetic flux tubes back to the visible world, and help them to tranform back to ordinary nuclei? Conductors in electric fields would thus help to transform dark nuclei to ordinary matter.
See the article Cold Fusion Again or the chapter with the same title.
For a summary of earlier postings see Links to the latest progress in TGD.